Feeling of Pungency: capsacins, thiocyanates, piperine
the pain increases sensitivity
Feeling of Astringency (dry/puckering): tannins
Aromatics (volatile, used to protect the plant)
Floral
Fruity - esters
Citrus
Green/Woody - fatty acids broken down
Nutty
Terpenes - herbaceous
Phenols - warming, spicy
antioxidant
slightly water soluble
tannins
Menthol
Sulfur - pungent
garlic onion
Acid, moldy, vinegar
Chemical
alcohol, ammonia
Temperature
Texture
4 molecules
water
protiens
amino acids
savory
gluten, gelatin
lipids
unsaturated
saturated
free fatty acids
phospholipids
lecithin
carbs
sugars
-itols have one end modified and metabolize slowly
maltodextrin is a 2 - 20 chain sugar that thickens
smaller sugars taste sweeter in general, hold on to water better, and brown more easily
starch
amylose - long starch chain
amylopectin - branched large chain
When heated with water starch expands because water hydrogen bonds to the starch. As it cools, the starch binds to itself again causing staling. Amylopecting is less susepctible to this because it doesn’t rebind as strongly
fiber
gums/pectin/inulin
Dispersions
Suspensions (will settle)
purees
Colloids (disperse light)
Emulsion (l in l)
Stabilized by emulsifiers, thickeners, and homogenization (making droplets smaller)
over stirring can disrupt emulsifiers e.g. butter
oil in water: mayonnaise, cream sauces, beurre blanc,
water in oil: vinaigrette
Foam (g in s/l)
Aerosol (s/l in g)
Gel (l in s)
Sol (s in l)
Starch: granules turn into amylose and form a web which traps granules (max thickness) and as heating continues the granules disappear. Can be added via a slurry or a roux (fat coating granules).
Solution (homogenous)
Gelatin: stocks such as demiglace, consomme
Heat and Reactions
Pyrolysis - heating without oxygen
ash - mineral solids
flammable gases (CH4, H2)
char (carbon solids)
charcoal is created by slow pyrolysis of wood which removes water
used as metallurgic fuel
tar (carbon solids in the air)
Combustion - flammable gasses are oxidized
Browning reactions
maillard between carbohydrate and amino acid
caramelization
assisted by alkaline conditions
Rancidification
Fats get oxidizedsalt and oxygen exposure
salt and O2 exposure
unsaturated fat is more prone
Convection, Conduction, Radiation Methods
water
boiling/poaching/sous vide/braise
fat
deep fry/confit
stir fry/pan fry
dry
grill/bbq/roast
oven/broil
Meats
Muscle Properties
75% water, 20% protein, 3% fat
Utilized muscles have thicker fibers and connective tissue, thus tougher
Fat stores distinguishing flavors affected by feed and quantity increases with age (gamey)
Dark/slow twitch requires more myoglobin which is red and is more fat
white/fast twitch has less fat since glycogen is used
Slaughter
Stunned and then bled to death
Hung to prevent rigor mortis from locking joints
Preservation
Aging allows proteases to soften meat and dry
Dehydration
Salt cured
brining will partially dissolve myosin
juicier because the salty meat absorbs more water
Nitrate reacts with hemoglobin to preserve pinkness and prevent iron from oxidizing fat
Hot/Cold smoking
Land
Anatomy
Arm: shank, brisket
Shoulder: chuck, blade
Breast: skirt, flank
Ribs
Loin: tenderloin, t-bone, sirloin
Leg: Round, rump
Thymus: Sweetbread
Stomach: Gizzard, tripe
Fat: tallow, lard, suet
Cooking
120F: proteins denature and become opaque
140F: Collagen contracts and squeezes water out. Myoglobin reacts with proteins and becomes less red. If sufficiently slow cooked, the reacting proteins will all be denatured and the meat can be done and red.
160F: Collagen melts into gelatin
Sea
Properties
Buyoancy
softer and less bones
less connective tissue
Cold blooded and cold environment: 5C
Unsaturated fats that stay liquid at low temperatures
Harbor enzymes and bacteria that function at low temperatures
cooks faster
Salinity: 3% salt compared to 1% normal mineral concentration by weight
increased amino acid and amine concentration in cells
amines get oxidized to ammonia
Unpredictable conditions
spawning causes fish to expend protein into eggs/sperm
Fish
Fat is usually in the belly and gets more lean towards back and tail
Mostly fast twitch in middle, and slow twitch near the skin
Species
Fatty Saltwater
Herring: Anchovy, sardine, sprat, shad
delicate, lots of enzymes
Salmon - sake
swim upstream to spawn
Mackerel - saba/aji
related to tuna
oily
Icefish/Chilean Sea Bass/Patagonian toothfish and Sablefish/Black Cod/butterfish
yolk has amaylase that must be boiled to deactivate so thickening starches can be added. Cooled without stirring to set the starch. flour allows for boiling
fruit curd
Foams
sugar increases time to make and stability of foam
acid decreases S-S bonds which squeeze out water
Meringue/Souffle
Mousse is meringue stabilized by chilled fats
Sabayon from yolks
require liquid and heat
Pickled
brine, vinegar, alkaline
Fruits and Vegetables
Anatomy
Color Chemicals
Chloropyhl
acid accelerates dulling
carotene
red/orange
anthocyanin
ph indicator
Tissue
ground
storage/photosynthesis
large vacuoles
vascular
xylem and phloem
tough/fibrous
dermal
secretory
Organs
Root
Stem/Stalk/Tuber/Rhizome
Leaves
Flower
Fruit (ovary containing seed)
climacteric fruits ripen after harvest via ethylene
pomes, tropical fruits, stone fruits, tomatoes
non-climacteric fruits do not
Seed
bran/seed coat
oils and protecting chemicals
slows passage of water significantly (main part of cooking is waiting for water to permeate)
endosperm/cotyledons (large storage leaves)
mostly starch and proteins
nuts and soybeans contain many seed oils
germ/embryo
oils
Preservation and Preparations
pickling with salt and acid
increase sugar concentration
ice water to reirrigate plant cells
blanching will deactivate enzymes
Vegtables
Roots/Tubers
Potato/Sweet Potato/Taro/Casava
starchy
high heat does not allow starch to absorb water
low heat will allow starch to absorb and glue the borders